Why does CH3Br react faster with hydroxyl ions (OH^-) than CH3Cl?

In the halogen series, Br has a weaker bond with the CH3 than Cl. Smaller halogen atoms have a larger electron affinity to fill the outer shell. The greater tendncey of CH3Br to break up into a CH3+ ion increases its reactivity with OH-

Chemistry is not my field of expertise, so you may get a better answer from another staff member.

To understand why CH3Br reacts faster with hydroxyl ions (OH^-) than CH3Cl, we need to consider the differences in the chemical properties of bromine (Br) and chlorine (Cl) atoms.

In the halogen series, the halogens become larger and have a greater number of electron shells as you move down the periodic table. This means that bromine (Br) is a larger atom compared to chlorine (Cl).

The size of the halogen atom affects its electron affinity, which is the energy released when an electron is added to the atom. Smaller halogen atoms generally have a higher electron affinity because their outer electron shells are closer to the positively charged nucleus and experience a stronger attraction.

In the case of CH3Br and CH3Cl, the bromine atom in CH3Br has a weaker bond with the methyl group (CH3) compared to the chlorine atom in CH3Cl. This is because the larger bromine atom has a more diffuse electron cloud, resulting in a weaker bond between the halogen and the methyl group.

This weaker bond in CH3Br makes it more likely for CH3Br to break apart into a CH3+ ion and a Br^- ion when reacting with hydroxyl ions (OH^-). The presence of CH3+ ion increases the reactivity of CH3Br with OH^-.

On the other hand, CH3Cl has a stronger bond between the chlorine atom and the methyl group due to the smaller size of chlorine. This stronger bond makes it less likely for CH3Cl to break apart into CH3+ and Cl^- ions when reacting with OH^-.

Overall, the larger bromine atom in CH3Br and its weaker bond with the methyl group increase its reactivity with hydroxyl ions compared to CH3Cl.

Remember that chemistry can be complex, and this explanation provides a simplified understanding. For a more thorough and comprehensive answer, it is always beneficial to consult a chemistry expert or refer to reliable sources in the field.