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The relative frequency of a non-defective calculator is the number of non-defective calculators divided by the total number of calculators.
Total calculators = 500
Non-defective calculators = 500 - 25 = 475
Relative frequency = Non-defective calculators / Total calculators
Relative frequency = 475 / 500
Simplifying this fraction, we get:
Relative frequency = 19 / 20
Therefore, the correct answer is B. 19/20.