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Using the formula for the volume of a cylinder, which is V = πr^2h, where r is the radius and h is the height:
Radius = width / 2 = 16 / 2 = 8 meters
V = 3.14 * 8^2 * 25
V = 3.14 * 64 * 25
V = 5024 cubic meters
Therefore, the volume of the water tower is 5,024 cubic meters.