To determine the concentration of magnesium hydroxide (Mg(OH)2) required to make a solution with a pH of 10.87, we need to consider the dissociation of magnesium hydroxide in water.
Magnesium hydroxide dissociates into one magnesium ion (Mg2+) and two hydroxide ions (OH-) in water according to the following equation:
Mg(OH)2(s) ⇌ Mg2+(aq) + 2OH-(aq)
The equilibrium constant expression for this dissociation is:
Ksp = [Mg2+][OH-]^2
Given that the desired pH is 10.87, we can use the fact that pH is related to the concentration of hydroxide ions (OH-) in solution. In a neutral solution, the concentration of hydroxide ions is equal to the concentration of hydronium ions (H+), which can be calculated using the equation:
pOH = 14 - pH
In this case, pOH = 14 - 10.87 = 3.13
Now, we convert pOH to the concentration of hydroxide ions using the equation:
[OH-] = 10^(-pOH)
[OH-] = 10^(-3.13)
[OH-] ≈ 7.23 x 10^(-4) M
Since the magnesium hydroxide dissociates into two hydroxide ions, the final concentration of magnesium hydroxide will be half the concentration of hydroxide ions:
[Mg(OH)2] ≈ 3.62 x 10^(-4) M
Therefore, a concentration of approximately 3.62 x 10^(-4) M of magnesium hydroxide is required to make a solution with a pH of 10.87.