The rate constant for this first-order reaction is 0.0570 s–1 at 400 °C.

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After how many seconds will 14.0% of the reactant remain?

To expand on Dr.Bob's answer:

The usual formula is:
ln([A-t]/[A-0]) = -kt
but you're looking for t so you have to rearrange the formula:
ln(concentration over 100)/-(k) = t
[ln(14/100)]/-0.0570 = t
34.36834015 = t
Your answer should be 34.4 seconds

Well, let me do some quick calculations. If the rate constant is 0.0570 s–1, that means the reaction is pretty quick. It's like a cheetah running through the savannah!

Now, to find out when 14.0% of the reactant will remain, we can use the first-order reaction equation:

ln(A₀/A) = kt

Where A₀ is the initial concentration of the reactant, A is the concentration at time t, k is the rate constant, and t is the time passed.

Since we want to find out when 14.0% of the reactant remains, that means we're looking for the time when A equals 0.14A₀.

So, we can rearrange the equation to solve for t:

ln(A₀/0.14A₀) = kt

Simplifying this equation a bit:

ln(1/0.14) = kt

Now we can plug in the values:

ln(1/0.14) = 0.0570 s–1 * t

Solving for t:

t = ln(1/0.14) / 0.0570 s–1

Doing the calculations, we find that t is approximately 56.63 seconds.

So, after about 56.63 seconds, 14.0% of the reactant will remain. But remember, this is no laughing matter! It's some serious chemistry!

To determine how many seconds it will take for 14.0% of the reactant to remain, we can use the first-order reaction rate equation:

ln([A]/[A]0) = -kt

Where [A] is the concentration of the reactant at a certain time, [A]0 is the initial concentration of the reactant, k is the rate constant, t is the time, and ln is the natural logarithm.

In this case, we are given the rate constant (k = 0.0570 s^–1) and we want to find the time (t) when 14.0% ([A]/[A]0 = 0.14) of the reactant remains.

Substituting the given values into the equation, we have:

ln(0.14) = -0.0570 s^–1 * t

To solve for t, we can rearrange the equation:

t = ln(0.14) / (-0.0570 s^–1)

Calculating this using a calculator, we find:

t ≈ 87.93 seconds

Therefore, it will take approximately 87.93 seconds for 14.0% of the reactant to remain.

ln(No/N) = kt

If you use No = 100, then N = 14, substitute k and solve for t.